Thermodynamics
and alternative energy
The
laws of thermodynamics
The
zeroth law of thermodynamics states that if two systems are both in thermal
equilibrium with a third system, then they are in thermal equilibrium with each
other. This law allows for definition of the empirical temperature as a system
property (Boundless, undated). Hence, if system 1 has the same temperature as
system 2 and system 2 has the same temperature as system 3, then the
temperature of system 1 is the same as that of system 3. Three systems that are
in thermal equilibrium have the same temperature, with the law allowing for
definition of empirical temperature.
The
first law of thermodynamics states that energy cannot be created or destroyed;
it can only be changed from one form to another form or transferred. For
example, kinetic energy in wind changes to mechanical energy and then to
electrical energy. This first law of thermodynamics is also known as the law of
conservation of energy (Cengel and Boles 2014).
The
second law of thermodynamics states that an isolated system’s entropy always
increases. This is because isolated systems, systems that neither matter nor
energy can pass through because of the enclosing boundaries, naturally evolve
towards thermal equilibrium. By achieving thermal equilibrium, the system
achieves maximum entropy. Notably, isolated system is hypothetical for
calculations only, since they do not really exist (Cengel and Boles 2014).
However, the universe is defined as an isolated system, with its entropy always
increasing.
The
third law of thermodynamics states that as a system’s temperature approaches
absolute zero, the system’s entropy approaches a constant value. This means
that there is typically no entropy in a system with 0 K temperatures, though
residual entropy based on the ground state of the system may exist (Boundless,
undated).
Thermodynamic
laws versus energy use, conversion and efficiency
Work
and heat usually happen when energy is captured while moving from an area of
high concentration to an area of low concentration, the unstoppable tendency of
energy. However, in certain circumstances such as compressed gas and
photosynthesis, the energy flow is reversed.
One
way to ensure most energy is channeled towards work is increasing thermal
efficiency (Cengel and Boles 2014). This is achieved by noting where energy
dispensed by a system ends up. Then a system’s conversion of energy into
useless energy (e.g. thermal energy from an engine) is reduced whereas conversion
into useful energy (e.g. mechanical energy) is increased.
While
energy does not get used up, its availability reduces. Hence we should be energy
efficient, aiming towards the unattainable 100% energy efficiency, by reducing
the number of conversions energy goes through (Boundless, undated). Thus if
kinetic energy can be directly converted to electrical energy there is no need
for it to go through mechanical energy form if all other factors are constant.
Pros
and cons of various energy types
The
nonrenewable fossil fuels are abundant, easily accessible and inexpensive. They
provide a lot of concentrated energy at relatively low cost e.g. gas is very
energy efficient. Crude oil and refined oil can easily be transported from
where it is extracted or to where it is needed using pipes. The main
disadvantage of fossil fuels is pollution (DeGunther, 2009). The pollution is
experienced through global warming (greenhouse effect), oil spills, odor and
acid rain. Mining of fossil fuel also leads to land destruction.
The
multi-step process of nuclear power stations improves energy efficiency while
suppressing the many negative byproducts of nuclear energy. Nuclear energy is
more reliable than other forms of energy, with a capacity to run for 540
uninterrupted days (DeGunther, 2009). Compared to fossil fuels, this energy is
less expensive to get and transport and its plants does not emit greenhouse
gases. However, uranium is a naturally unstable element that must be carefully
handled to avoid radiation. The radioactive nuclear byproducts can also lead to
contamination and pollution, with heated water from nuclear plants adversely
affecting the ecosystem. Abandoned
nuclear reactors also pose a huge challenge since they cannot be removed yet
take up valuable space.
Solar
energy is a silent, renewable, clean energy until when the sun runs out in
several billion years’ time as predicted (DeGunther, 2009). This makes its use
get good tax credits from the federal government. Solar panels also require
little maintenance with largely reliable mechanical parts. Nonetheless,
installation of solar panels can be expensive albeit the free energy. Yet,
conversion of sun rays to energy is quite inefficient although new technology
is improving this. A major disadvantage is the reduced performance of solar
panels during cloudy days and at night though new technology is gradually
improving the capacity to store solar energy.
Wind
is free and is energy efficient. This renewable energy does not cause pollution,
although manufacture of wind turbines does cause some pollution. Wind turbines
also do not ‘ debatable with some arguing that the turbines are unsightly) coexisting
with other activities e.g. farming (DeGunther, 2009). Just like solar panels,
the turbines are in different sizes to fit different requirements and budgets
and can be installed independently of the power grid to serve remote areas. Usually,
the bigger the turbine, the noisier it is. Wind strength is also inconsistent
and the turbine may not produce power in certain instances. The increased frequency
of hurricanes and cyclones has also raised a safety concern of wind energy.
Hydropower
is a clean, renewable energy that does not pollute the environment. Unlike wind
power, hydropower is available when needed. Apart from providing energy, the
water reservoirs are important for supplying water (e.g. for irrigation) and
controlling flooding. They can also be used for recreational purposes such as
fishing, swimming and sightseeing. However, hydropower plants can easily be
impacted by droughts. They also affect the riparian communities by affecting
water quality, water flow and land use. Fish populations may also be affected
to the impact on fish migration. Construction of hydropower plants is also
relatively expensive and can lead to environmental damage e.g. earthquakes
caused by Hoover Dam.
Biofuels
are a renewable energy with less greenhouse gases compared to fossil fuels,
with some estimating a 65% reduction. This energy is easily available being got
from plants, crop waste or manure (DeGunther, 2009). Biofuels enhance a
country’s economic security because of less dependence on imported oil.
However, producing biofuels is costly and fertilizers lead to water pollution.
It may also lead to monoculture and consequent soil degradation.
Energy
Policy Act of 2005
The
Energy Policy Act of 2005 aims to curb problems posed by the need for more
energy by improving supply. One provision is authorizing tax credits for
producers of alternative energy (USCHR, 2005). This excludes fossil fuels but
includes all the other energies including nuclear energy. It especially rewards
producers of clean, renewable energy.
Because
of this provision, there has been increasing market adaption, investment and
job creation in alternative energy because of decreased pay-off time. Academic,
commercial and government sectors are conducting advanced research in this
field with a view to improving energy efficiency and increasing total energy
production ((BOEM, undated).
The
Production Tax Credit (PTC) reduces the federal income tax paid by alternative
energy projects that connect to the power grid, the Investment Tax Credit (ITC)
reduces federal income tax paid by those who invest on alternative energy
projects, and the Advanced Energy Manufacturing Tax Credit (MTC) awards tax
credits to facilities that advance clean energy.
Sandia
National Laboratories and the National Renewable Energy Laboratory (NREL)
funded and supported by the Department of Energy and corporations are two
prominent organizations in alternative energy. As a result of the research and
adoption of alternative energies such systems as the Plug-in Hybrid Electric
Vehicles (PHEV) are on the rise (BOEM, undated).
Another
provision of the Energy Policy Act is authorization of the Department of the
Interior to grant leases for energy production, transportation or transmission
on the Outer Continental Shelf lands from sources other than fossil fuels (USCHR,
2005). This has led to initiation of development of offshore facilities (notably
in the Gulf of Mexico) for alternative fuels – especially wind, wave and ocean
current technologies. When these developments become fully operational, they
will contribute much clean energy to the power grid. They will also increase
adaption of components and systems that use alternative energy. Moreover it
will increase United States’ security, independence and health due to less
reliance on foreign fossil fuel.
References
BOEM.
(undated). Guide to the OCS Alternative Energy Final Programmatic Environmental
Impact Statement. http://www.boem.gov/Renewable-Energy-Program/Regulatory-Information/Guide-To-EIS.aspx.
Accessed on August 1, 2016.
Boundless.
(undated). The Three Laws of Thermodynamics. Boundless Chemistry. https://www.boundless.com/chemistry/textbooks/boundless-chemistry-textbook/thermodynamics-17/the-laws-of-thermodynamics-123/the-three-laws-of-thermodynamics-496-3601/.
Accessed on August 2, 2016.
Cengel,
Y. and Boles, M. (2014). Thermodynamics: An Engineering Approach 8th Edition.
New York: McGraw-Hill Education.
DeGunther,
R. (2009). Alternative Energy for Dummies. New York: Wiley.
USCHR.
(2005). Energy Policy Act of 2005. http://energy.gov/sites/prod/files/2013/10/f3/epact_2005.pdf.
Accessed on August 2, 2016.
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